The Anode is the negative or reducing electrode that releases electrons to the external circuit and oxidizes during and electrochemical reaction. In a lithium ion cell the anode is commonly graphite or graphite and silicon.

Lithium ion cell

Lithium Ion Cells

When discharge begins the lithiated carbon releases a Li+ ion and a free electron. Electrolyte, that can readily transports ions, contains a lithium salt that is dissolved in an organic solvent. The Li+ ion, which moves towards the electrolyte, replaces another Li + ion from the electrolyte, which moves towards the cathode. At the cathode/electrolyte interface, Li+ ions then become intercalated into the cathode and the associated electron is used by the external device.