Stack Pressure & Interfacial Resistance for Pack Designers

Solid state cell interfacial pressure - pencil drawing of a huge press

Every solid-state chemistry roundup mentions that cells need “stack pressure,” usually as a single line in a spec table. What that line means for the person actually designing the pack around the cell: This gets skipped almost everywhere. This is the pack-design follow-on to our cell-level piece on What’s the right stack pressure?, which covers … Read more

AI-Guided Materials Discovery: Bayesian Optimisation for Electrolyte Formulation

Closed-loop diagram of Bayesian optimisation for autonomous electrolyte formulation discovery: propose candidate, robotic synthesis, measure performance, update model

Choosing a solvent blend or additive package is fundamentally a search problem: a handful of components, each at a continuous concentration, combine into a space with far more candidate formulations than anyone could test by hand. The Electrolyte Solvent Ratios and Electrolyte Additives pages describe what’s in that space and why each component matters. This … Read more

Grain Boundary Dendrite Growth in Solid-State Electrolytes

grain boundaries and dendrites in solid state

Lithium dendrites growing through a solid electrolyte do not behave like the diffuse, roughly uniform plating seen at a liquid electrolyte interface. In a polycrystalline ceramic or a cold-pressed sulfide pellet, the microstructure itself dictates where lithium goes: dendrites overwhelmingly nucleate and propagate along grain boundaries rather than through the bulk of individual grains, even … Read more

Engineering the LFP Cathode-Electrolyte Interface

three routes to LFP-CEI engineering

The reference page on LFP’s cathode-electrolyte interface covers coatings and doping as the two established levers. There is a third, newer one that deserves its own look: treating the CEI itself, or the process that forms it, as the thing being engineered. Three recent papers take genuinely different routes to that same goal, and reading … Read more

Galvanic vs Electrolytic

Galvanic vs Electrolytic behaviour poster

Since I know that this is a delicate topic, and many get confused, I will explain very briefly the nomenclature that I used. The IUPAC defines the anode as the electrode at which the oxidation occurs and the cathode as the electrode at which the reduction occurs. Therefore, in a galvanic cell, the negative electrode … Read more

Cobalt-Free, Anode-Free: A Simpler Route to High-Energy Cells?

Amode Free LNO

Anode-free lithium batteries take “delete the anode” to its extreme: instead of shipping graphite or a lithium foil, the cell starts with bare copper on the negative side. All the lithium comes from the cathode on first charge and plates itself onto that copper. Removing the graphite host lifts both gravimetric and volumetric energy density, … Read more

The Form Factor Dilemma in High-Silicon Anodes: Structural Rigidity, Porosity Loss, and Plating Risk

AION Engineering INC While silicon (SiOx/SiC/Si) based anodes skyrocket battery capacity, their swelling character reaching up to 300% volume expansion transforms cell design from a purely electrochemical challenge into a brutal mechanical packaging problem. It is not just about how much lithium the active material can store; how the casing structurally resists (its rigidity) when … Read more