The fundamental relationship between a cell’s open circuit voltage, internal resistance, and terminal voltage under load. The most-used equation in pack electrical design. See the Thevenin Model for how internal resistance is modelled in more detail, including its split into ohmic and polarisation components.
Where:
- Vₜ = terminal voltage (V) — voltage at cell terminals under load
- OCV = open circuit voltage (V) — equilibrium voltage at rest
- I = current (A) — positive for discharge, negative for charge
- Rint = internal resistance (Ω)
- On charge: Vₜ = OCV + (I × Rint)
See also: Kirchoff Laws, Watt Hour