Engineering the LFP Cathode-Electrolyte Interface

three routes to LFP-CEI engineering

The reference page on LFP’s cathode-electrolyte interface covers coatings and doping as the two established levers. There is a third, newer one that deserves its own look: treating the CEI itself, or the process that forms it, as the thing being engineered. Three recent papers take genuinely different routes to that same goal, and reading … Read more

Galvanic vs Electrolytic

Galvanic vs Electrolytic behaviour poster

Since I know that this is a delicate topic, and many get confused, I will explain very briefly the nomenclature that I used. The IUPAC defines the anode as the electrode at which the oxidation occurs and the cathode as the electrode at which the reduction occurs. Therefore, in a galvanic cell, the negative electrode … Read more

New Insights into how Cathodes Store Energy

New Insights into how Cathodes Store Energy

Led by Dr. Galo J. Páez Fajardo and Professor Louis F. J. Piper, the paper addresses a fundamental question in battery science: how exactly do lithium-ion battery cathodes store and release energy at the sub-nanoscale?. Páez Fajardo, G.J., Dogaru, D.E., Banerjee, H. et al. Direct evidence of metal–ligand redox processes in positive electrodes during lithium-based battery operation. Nat. … Read more

Electrode Coating Techniques: From Lab to Gigafactory

Doctor Blade Coating

AION Engineering INC 1. Doctor Blade Coating Classification: Self-Metered Process Best For: Material screening, coin cells, basic R&D. Doctor blade coating is the foundational technique for battery research. It relies on a “self-metered” mechanism, meaning the final wet film thickness is determined by the geometric gap between the blade and the substrate, combined with the … Read more

Cathode Coating Porosity and ASR

ASR and porosity

AION Engineering INC Why High Porosity Can Lower Resistance in Power Cells Introduction Area Specific Resistance (ASR) is one of the most important performance indicators in lithium ion cathodes. Engineers often assume that reducing porosity improves conductivity and therefore lowers ASR. This idea comes from the expectation that a denser structure provides better particle contact … Read more

Calender Roll Temperature versus Chemistry

roll temperature and force schematic image

So what is the optimum calender roll temperature versus chemistry? We looked at a number of papers to offer an initial roll temperature and reasoning behind it. This is not extensive and as we have seen there are a number of other aspects that need to be considered such as energy use, LCA and capital … Read more

Relation Between Silicon-Based Additives in the Anode and the Gap Between Jelly Roll and Can

graph of Si additive and gap between jelly roll and can in a cylindrical cell design

AION Engineering INC All cells discussed here are 18650 NMC cells. Balancing Energy Density and Safety Using silicon-based additives in the anode requires a delicate trade-off in cell design. While silicon increases the energy density, it also brings significant challenges for cell safety. Why More Space is Needed Silicon expands and contracts during charge-discharge cycling, … Read more

Why N/P Ratio Matters in Lithium-Ion Cells

NP ratio

AION Engineering INC What is the N/P Ratio? The N/P ratio refers to the ratio between the effective capacity of the anode (negative electrode, N) and the cathode (positive electrode, P). In simple terms, it compares how much lithium the anode can store versus how much the cathode can provide. For a safe and reliable … Read more

Importance of Electrode Parameter Changes After Calendaring in Lithium-Ion Cell Production

AION Engineering INC Calendaring is a crucial step in lithium-ion battery manufacturing, where electrodes are compressed to reduce porosity and increase density. Optimizing this process directly impacts the performance, longevity, and efficiency of the final cell. Why Calendaring Matters The primary goals of calendaring are: Effectively, proper calendaring ensures a balance between mechanical stability, electrochemical … Read more

The Influence of NMC Composition on Li-ion Cell Performance

as Ni content of NMC chemistry increases the energy density of the battery cell increases

AION Engineering INC The performance of a lithium-ion cell is fundamentally governed by its material chemistry, particularly the composition of its cathode active material (CAM). In this article, we focus specifically on the role of nickel content in Nickel Manganese Cobalt Oxide (NMC) materials and how it correlates with energy density and power capability. Although … Read more