Thermal Runaway vs Electrical Energy

The energy released during Thermal Runaway versus the electrical energy stored in a battery.

The energy released during Thermal Runaway (TR) versus the stored electrical energy. A number has been bandied around for a long time that the energy released in a TR event was 2 to 6 times the electrical energy stored in the cell.

There are a lot of papers published where the heat release from a cell has been measured or estimated during thermal runaway. There have also been measurements of numerous chemistries and states of charge etc.

One option was to just grab all of this data and plot the TR thermal energy release against the electrical energy stored in the cell prior to this event being triggered.

Warnings: this ignores differences between chemistry, cell format and how the energy released was determined. Hence this is just an interesting plot and an interesting straight line data fit to see if the 2 to 6 times electrical energy has any merit.

Thermal Runaway Energy vs Electrical Energy

This data includes different chemistries, results versus SoC and different size / formats of cell. However, as a check of the rule of thumb it shows that the energy released in Thermal Runaway is 2x the electrical energy stored in the cell.

At the bottom end of this graph there is a lot more data as most tests are run on small cells (up to around 20Ah).

thermal runaway energy vs electrical energy for smaller cells

However, the temperature at which the cell goes into thermal runaway, the rate at which the energy is released and the nature of that release can be very variable.

This shows the importance of measuring the energy release in thermal runaway and using that to understand how to design and manage the cell you have selected.

This post has been built based on the support and sponsorship from: Eatron TechnologiesAbout:EnergyAVANT Future MobilityQuarto Technical Services and TAE Power Solutions.

Rappsilber et al [6] have done a quantitative and qualitative analysis of 135 scientific papers looking at heat and gas release during thermal runaway. The following graph shows some much higher values for total heat release, we have added total heat released per unit of electrical energy in (Wh/Wh )values to make it easier to compare. Note 3.6kJ = 1Wh.

total heat release versus electrical energy for different chemistries

References

  1. Joshua Lamb et al, Investigating the Role of Energy Density in Thermal Runaway of Lithium-Ion Batteries with Accelerating Rate Calorimetry, 2021 J. Electrochem. Soc. 168 060516
  2. Xuan Liu, COMPREHENSIVE CALORIMETRY AND MODELING OF THE THERMALLYINDUCED FAILURE OF A LITHIUM ION BATTERY, Doctor of Philosophy, 2016, University of Maryland
  3. Chunjing Lin, Fang Wang, Bin Fan, Shan Ren, Yuemeng Zhang, Liqiong Han, Shiqiang Liu, Sichuan Xu, Comparative study on the heat generation behavior of lithium-ion batteries with different cathode materials using accelerating rate calorimetry, Energy Procedia, Volume 142, 2017
  4. Battery Failure Databank, NREL
  5. S. Hoelle et al, Analysis on Thermal Runaway Behavior of Prismatic Lithium-Ion Batteries with Autoclave Calorimetry, 2021 J. Electrochem. Soc. 168 120515
  6. Tim Rappsilber, Nawar Yusfi, Simone Krüger, Sarah-Katharina Hahn, Tim-Patrick Fellinger, Jonas Krug von Nidda, Rico Tschirschwitz, Meta-analysis of heat release and smoke gas emission during thermal runaway of lithium-ion batteries, Journal of Energy Storage, Volume 60, 2023

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